A novel n-pivot macrocyclic ligand and its Cobalt(II) phthalocyanine derivative: synthesis, characterization and extractant properties

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dc.creatorGök, Halil Zeki; BUCAK TEKNOLOJİ FAKÜLTESİ
dc.creatorGök, Yaşar; BUCAK TEKNOLOJİ FAKÜLTESİ
dc.date2018-11-20T00:00:00Z
dc.date.accessioned2019-04-09T07:22:20Z
dc.date.available2019-04-09T07:22:20Z
dc.descriptionIn thisstudy, the synthesis of a novel N-pivot 12-membered macrocyclic ligand withmixed donor atoms 2, which is aphthalonitrile derivative, and a new cobalt(II) phthalocyanine complex 3 obtained by cyclotetramerizationreaction of  2 were described.  Newly synthesizedcompounds were characterized by using several spectroscopic techniques such asIR, UV-Vis, 1H and 13C NMR, MS and elemental analysis.These macrocyclic systems 2 and 3 were investigated as extractants inliquid-liquid extraction technique to reveal metal ion binding capabilitytowards transition metals such as Ag(I), Hg(II), Cd(II), Zn(II), Cu(II),Ni(II), Pb(II) and Co(II). The highestextractability from aqueous phase to organic phase was found for Hg(II) cationover the other metal cations with cobalt(II) phthalocyanine 3. The extraction percentage of Hg(II)cation from aqueous phase to chloroform in the presence of cobalt(II)phthalocyanine 3 as extractant wasfound as 96.0%. 
dc.formatapplication/pdf
dc.identifierhttp://dergipark.gov.tr/sjmakeu/issue/39887/465820
dc.identifier
dc.identifier.urihttp://hdl.handle.net/11672/2484
dc.languageen
dc.publisherMehmet Akif Ersoy University
dc.publisherMehmet Akif Ersoy Üniversitesi
dc.relationhttp://dergipark.gov.tr/download/article-file/566853
dc.sourceVolume: 1, Issue: 2 40-45
dc.source2651-3722
dc.subjectPhthalocyanine,Macrocycle,N-Pivot,Transition metal,Solvent extraction
dc.titleA novel n-pivot macrocyclic ligand and its Cobalt(II) phthalocyanine derivative: synthesis, characterization and extractant properties
dc.typeinfo:eu-repo/semantics/article

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Scientific Journal of Mehmet Akif Ersoy University